You can use the CDBurn.exe tool from Microsoft. It is included in the Windows Server 2003 Resource Tools.
You can even use this tool to erase CDRW discs.
Command Line Syntax:
cdburn <drive> image [options]
-erase Erases the disk before burning (valid for R/W only)
-sao Writes the image out in "session at once", or cue
sheet, mode (default is "track at once")
-speed Speed of burn, or ‘max’ for maximum speed
-imagehaspostgap Use if your image already contains a 150 sector postgap
The [image] must be provided unless the -erase flag is set.
If both an image and -erase are provided, the media will be
erased prior to burning the image to the disc.
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